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Imperial, boots that are actually used for walking around in (even if just during a scene) are probably not very safe for anal fucking. Most boot heels have some sharp (or at least rough) points, and they probably have a variety of unpleasant substances on them. My guess is that if you saw it in a porn film, they used a boot that they had specially prepared for the purpose by sanding the heel down. Remember that porn films usually edit out all the safety procedures.
Has your mistress trained you in how to get her boots on and off? Every good slave should learn this and perform it as a service, since boots can be an effort to put on and take off, especially in tight-fitting leather outfits.
Here's the basic process as it's done by gay leathermen. For a leatherwoman, the process might be slightly different, but you too can explore and improvise the details.
When a boy puts my boots on (and these are army boots, just go up to mid-calf. Thigh-highs might require something else), I sit down and hold out my leg. My boy stands facing away from me straddling my leg and tightens his legs around mine so that my leg is supported by his (it's tiring holding a leg out like that without support). He straightens my sock, brushes any dirt off the sole of my foot, and has me angle my foot down (so the toes are pointed outward rather than up). He then looses the boot and slides it over my foot (which takes real practice on both parts to achieve). He then tightens the laces snuggly (checking with me to make sure it's not too tight), wraps the laces around my calf (they're pretty long laces), and ties them. Then we repeat with the other foot.
There are lots of things you could add to this process, depending on the dynamics of your mistress' boots. You might kneel and kiss the feet before and/or after putting the boots on. You might beg permission to touch her feet or her boots before you start. You might give them a quick polish before or after. And, of course, since your ass is facing your mistress, you ought to be working out to make it a pleasant view for her.
In particular, I recommend this anytime you two go out in leather (or even just for a nice dinner or whatever). Once she's dressed, go over her outfit with a lint roller or a soft cloth to remove any lint or stray dirt. Check to see if everything looks straight and smooth and either point it out to her or fix it yourself. It's your job to make your mistress look as hot and sexy as possible (or as presentable for work or a vanilla social occasion);if she doesn't look good, it reflects poorly on you. And if she looks hot and sexy and dominant, it's something you should take pride in. "That hot sexy dom/me is my master/mistress! S/he chose me out of all the possible subs!"
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